| Date | Home | Away | Result |
|---|---|---|---|
| 9/12/25 2:00 PM | FC Sevilla | FC Elche | 2-2 |
| 9/13/25 7:00 AM | FC Getafe | Real Oviedo | 2-0 |
| 9/13/25 9:15 AM | Real Sociedad | Real Madrid | 1-2 |
| 9/13/25 11:30 AM | Athletic Bilbao | Deportivo Alaves | 0-1 |
| 9/13/25 2:00 PM | Atletico Madrid | FC Villarreal | 2-0 |
| 9/14/25 7:00 AM | Celta Vigo | FC Girona | 1-1 |
| 9/14/25 9:15 AM | UD Levante | Real Betis Sevilla | 2-2 |
| 9/14/25 11:30 AM | CA Osasuna | Rayo Vallecano | 2-0 |
| 9/14/25 2:00 PM | FC Barcelona | FC Valencia | 6-0 |
| 9/15/25 2:00 PM | Espanyol Barcelona | RCD Mallorca | 3-2 |